Product ID:74-32/68, VANDAL MARK REMOVER (GEL)
MSDS Date:09/17/1990
FSC:7930
NIIN:00N031807
MSDS Number: BPJYM

MIDCO PRODUCTS CO INC

11697 FAIRGROVE IND BLVD
MARYLAND HEIGHTS, MO 63043
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 314-567-1710

Preparer: GEORGE LAMB

Cage: 0BTA6

MIDCO PRODUCTS CO INC

MARYLAND HEIGHTS, MO 63043 US

Telephone: 314-567-1710

Cage: 0BTA6

ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 5-10%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

ETHANOL, 2-(2-ETHOXYETHOXY)-; (DIETHYLENE GLYCOL MONOETHYL

CAS: 111-90-0

RTECS: KK8750000

Fraction By Weight: 10-20%

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

PROPANE, 2-METHYL-; (ISOBUTANE)

CAS: 75-28-5

RTECS: TZ4300000

ACGIH TLV: 800 PPM (MFR)

CHLOROCARBONS . ANIMAL STUDIES HAVE CLEARLY

RTECS: 9999999ZZ

HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER ASSOC

RTECS: 9999999ZZ

(EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118 .

RTECS: 9999999ZZ

OF OCCUP REPROD HAZ. SEEK CONSULTATION FROM APPROP

RTECS: 9999999ZZ

SAFE HNDLNG & EXPOS RECOMMENDATIONS . RSLTS OF LAB

RTECS: 9999999ZZ

BENIGN TUMORS IN RATS EXPOSED TO 500 PPM; CANCER IN

RTECS: 9999999ZZ

IN HAMSTERS.

RTECS: 9999999ZZ

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 5-10%

OSHA PEL 500 PPM; 1000, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 15-25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL ALCOHOL; (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:OVEREXP TO METHYLENE CHLORIDE CAN
RAISE LEVEL OF CO IN BLOOD CAUSING CARDIOVASCULAR STRESS.
EPIDEMIOLOGY STUDIES FAILED TO SHOW TUMORIGENIC RESPONSE IN PLANT
WORKERS. METHYLENE CHLORIDE IS NOT BELIEVE D TO POSE MEASURABLE
CANCER RISK TO MANWHEN HNDLD AS LOW DEGREE OF MATERNAL &
EMBRYOTOXICITY AT 4500 (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: GROUP 2B (IARC),
ANTICIPATED TO BE A CARCINOGEN (NTP).
Effects of Overexposure:HLTH HAZ:PPM, NO TERATOLOGICAL EFTS & NO EFTS
ON REPROD AT CONC OF 4500 & 1225 PPM. EYES:MOD TO SEV IRRIT. SKIN:
IRRIT DUE TO DEFATTING OF TISS. INGEST:NAUS, HDCH & VOM.
INHAL:NAUS, DIZZ, COORDINATION IMPAIREMNT ON LONG EXPOS. OVEREXP
TO METHYLENE CHLORIDE HAS APPARENTLY BEEN FOUND TO CAUSE FOLLOWING
EFTS IN (SUPP DATA
Medical Cond Aggravated by Exposure:SKIN SENSITIVITY & CHEMICAL
ALLERGIES.

First Aid:EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS &
GET MD. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING.
INGEST:DO NOT INDUCE VOMITING. GET MD. INHAL:REMOVE TO FRESH AIR.
GIVE O2 IF BREATHING IS DIFFICULT. GET MD.

Extinguishing Media:CO2, STANDARD FOAM, DRY CHEMICAL & HALON.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOS TO TEMPS OVER 120F MAY CAUSE
BURSTING OR VENTING. HEAT/FIRE MAY CAUSE HAZ FUMES: CO, PHOSGENE,
AND HYDROGEN CHLORIDE.

Spill Release Procedures:SMALL SPILL:MOP UP & SOAK UP IMMEDIATELY.
REMOVE TO OUTDOORS. LARGE SPILL:EVACUATE AREA. CONTAIN LIQUID;
TRANSFER TO CLOSED METAL CONTAINERS. KEEP OUT OF WATER SUPPLY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE WHERE TEMPERATURES EXCEED
120F. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:NOT REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION RECOMMENDED TO MAINTAIN THE LEVEL OF
THE HAZARDOUS INGREDIENTS TO LESS THAN HALF OF THE TLV.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:LAB ANIMALS:LIVER ABNORMALITIES & LUNG DAMAGE.
CHLOROCARBON MATL HAVE PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE
IN LAB ANIMALS & COULD HAVE A SIMILAR EFT IN HUMANS. ADRENOMIMETICS
(E. G. EPINEPHRINE MAY BE CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO (ING
8)

HCC:G3
Vapor Pres:55 PSIG
Vapor Density:>1
Spec Gravity:0.88 (H2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:EMULSIFIABLE
Appearance and Odor:WATER WHITE GEL-SWEET ETHEREAL ODOR

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS. POSSIBLY SODIUM, POTASSIUM AND MAGNESIUM.
Stability Condition to Avoid:SOURCES OF HEAT.
Hazardous Decomposition Products:OPEN FLAMES CAN CAUSE THERMAL
DEGRADATION WITH THE EVOLUTION OF HYDROGEN CHLORIDE, PHOSGENE, AND
CHLORINE.

Waste Disposal Methods:DISPOSE OF IN A MANNER APPROVED BY LOCAL, STATE
& FEDERAL REGULATIONS AS WELL AS EPA STANDARDS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.